Benzisotriazole

  • Superior Corrosion Protection: Forms a stable, compact passivation film on copper, brass, bronze, silver and their alloys, effectively preventing oxidation, tarnishing and corrosion in water, humid air and underwater environments.

  • High Purity & Consistent Quality: Assay ≥ 99.5% with tight batch-to-batch control (water ≤ 0.1%, ash ≤ 0.05%), ensuring stable performance in every formulation.

  • Cost-Effective at Low Dosage: Highly efficient inhibition at low concentrations, reducing total formulation and treatment costs.

  • Excellent Thermal & Oxidative Stability: Withstands high-temperature and long-term service conditions; resistant to UV light degradation, extending product life in coolants, lubricants and coatings.

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Products Description

Benzotriazole (BTA) is a white to light yellow crystalline powder widely recognized as one of the most effective corrosion inhibitors for copper, silver and their alloys. It works by forming a stable, compact protective film (passivation layer) on metal surfaces, effectively preventing oxidation, tarnishing and corrosion even under humid or underwater conditions. With outstanding thermal and oxidative stability, UV resistance and low toxicity, BTA is a versatile chemical auxiliary used across water treatment, metalworking, antifreeze, lubricants and polymer industries.Sigma-AldrichSinochem Middle East Corporation.

Benzisotriazole

Chemical Properties

Property

Value

Melting point

97–99 °C (lit.)

Boiling point

204 °C (15 mmHg)

Density

1.36 g/cm³

Bulk density

500 kg/m³

Vapor density

4.1 (vs air = 1)

Vapor pressure

0.04 mmHg (20 °C)

Refractive index

1.5589 (estimate)

Storage temp.

Store below +30 °C

Solubility

19 g/l

Form

Powder, granules, crystals, needles or flakes

pKa

1.6 (at 20 °C)

Color

White to yellow-beige

Odor

Slight characteristic odor

pH

6.0–7.0 (100 g/l, H₂O, 20 °C) suspension

Explosive limit

2%

Water solubility

25 g/l in water (20 °C)

Merck

14, 1108

BRN

112133

Stability

Stable, but may be light sensitive. Incompatible with strong oxidizing agents, heavy metals.

InChIKey

QRUDEWIWKLJBPS-UHFFFAOYSA-N

LogP

1.34 (at 22.7 °C)

CAS DataBase Reference

95-14-7 (CAS DataBase Reference)

NIST Chemistry Reference

1H-Benzotriazole (95-14-7)

EPA Substance Registry System

1,2,3-Benzotriazole (95-14-7)

Benzisotriazole

Safety Information

Field

Value

Hazard Codes

Xn, Xi, F

Risk Statements

20/22-36-52/53-5-36/37/38-20/21/22-11

Safety Statements

26-36/37-61-45-36/37/39-28A

RIDADR

2811

WGK Germany

1

RTECS

DM1225000

Autoignition Temperature

400 °C

Hazard Note

Harmful / Irritant

TSCA

TSCA listed

HS Code

29339990

Hazardous Substances Data

95-14-7 (Hazardous Substances Data)

Toxicity

LD50 (oral, rabbit): 560 mg/kg; LD50 (dermal, rabbit): > 2000 mg/kg

Benzisotriazole

Product Applications

  • Corrosion Inhibitor: Protects copper, brass, bronze, silver and other metals in industrial water treatment systems (cooling water, boilers), circulating water treatment and closed-loop heating/cooling systems.

  • Antifreeze & Coolant Additive: Extends the service life of metal components in automotive antifreeze, radiator coolants, aircraft deicing and antifreeze fluids.

  • Metalworking Fluids & Lubricants: Used as a rust inhibitor and vapor-phase corrosion inhibitor in cutting fluids, hydraulic oils, gear oils, brake fluids, transformer oils and greases.

  • Polymer Additive: Imparts UV resistance and anti-static properties to polyester, polyamide and other high-molecular materials.

  • Photographic Chemicals: Serves as an antifogging agent (restrainer) in photographic emulsions; also used as an analytical reagent for silver determination.

  • Electroplating & Metal Surface Treatment: Used as a brightening and anti-tarnishing agent.

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