Cumyl Hydroperoxide CAS#80-15-9
Cumene hydroperoxide, an organic peroxide, appears as a colorless to light yellow or green liquid with a mild odor. Molecular weight = 152.21; Boiling point = 153℃; Freezing/Melting point = 2–10℃. It may explode when heated; Flash point = 79℃. Its explosive limits are: LEL = 0.9%; UEL = 6.5%. Hazard Classification (according to the NFPA-704 rating system): Health 1, Flammability 2, Reactivity 4 (Oxidizer). Slightly soluble in water.

Cumyl Hydroperoxide Chemical Properties
| Melting point | -30 °C |
| Boiling point | 100-101 °C/8 mmHg (lit.) |
| density | 1.03 g/mL at 25 °C |
| vapor density | 5.4 (vs air) |
| vapor pressure | <0.03 mm Hg ( 20 °C) |
| refractive index | n |
| Fp | 192 °C |
| storage temp. | 2-8°C |
| solubility | Chloroform (Soluble), Ethyl Acetate (Slightly), Methanol (Soluble) |
| form | clear liquid |
| pka | pK1:12.60 (25°C) |
| color | Colorless to Almost colorless |
| PH | >5 (20°C, 13g/L in H2O) |
| Water Solubility | Slightly soluble |
| BRN | 1908117 |
| Exposure limits | No exposure limit is set. On the basis of its irritant properties, a ceiling limit of 2 mg/m3 (0.3 ppm) is recommended. |
| Stability: | Stable. combustible. Strong oxidizer. Incompatible with a variety of organic materials, reacting vigorously or violently with acids, reducing agents, many metals, strong alkalies. Heat sensitive, decomposing explosively. |
| LogP | 1.6 at 25℃ |
| CAS DataBase Reference | 80-15-9(CAS DataBase Reference) |
| NIST Chemistry Reference | Hydroperoxide, 1-methyl-1-phenylethyl(80-15-9) |
| EPA Substance Registry System | Cumene hydroperoxide (80-15-9) |
Safety Information
| azard Codes | O,T,N |
| Risk Statements | 7-21/22-23-34-48/20/22-51/53-66-65-10-37 |
| Safety Statements | 14-3/7-36/37/39-45-50-61-14A-26-62-47-7 |
| RIDADR | UN 3109 5.2 |
| WGK Germany | 3 |
| RTECS | MX2450000 |
| TSCA | Yes |
| HazardClass | 5.2 |
| PackingGroup | II |
| HS Code | 29096000 |
| Hazardous Substances Data | 80-15-9(Hazardous Substances Data) |
Product Applications
Cumene Hydroperoxide is utilized in producing polystyrene nanocapsules. It functions as a curing agent for polyester resins and an oxidizing agent in organic chemical processes. It acts as an initiator for free-radical polymerization, particularly involving acrylate and methacrylate monomers. It is also used as an intermediate in the cumene process to produce phenol and acetone from benzene and propene. Additionally, it serves as an epoxidation reagent for allylic alcohols and fatty acid esters. Furthermore, it is employed in the production of methylstyrene, acetophenone, and cumyl alcohol.
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