Polymaleic Acid CAS#26099-09-2

  • Excellent threshold scale inhibition & crystal distortion effect, strongly suppress calcium carbonate, calcium phosphate scale in high-hardness, high-alkalinity water systems

  • Outstanding thermal stability, effective under high temperature conditions, ideal for boilers, circulating cooling water and flash desalination units

  • Good chlorine / oxidizing biocide tolerance, keeps stable performance in water systems with chlorination disinfection

  • Phosphorus-free polymer water treatment chemical, meets increasingly strict environmental discharge requirements

  • Good compatibility with zinc salts, phosphonates and other water treatment agents; enhances corrosion inhibition when compounded

  • Water-soluble low-molecular polycarboxylate, also works as dispersant for oilfield water injection, textile and industrial cleaning formulations

  • Stable liquid specification, easy dosing and dilution, consistent quality for bulk export

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Products Description

Polymaleic acid (PMA) is a homopolymer derived from maleic acid and exhibits excellent stability in the presence of chlorine and other oxidizing biocides. It possesses effective scale-inhibition properties and good thermal resistance, making it suitable for applications in water desalination plants. It is particularly effective as a calcium carbonate antiscalant under high-temperature conditions and in highly alkaline cooling water systems. Furthermore, polymaleic acid can be combined with zinc salts to enhance corrosion inhibition. Other applications include its use as a concrete additive and in crude oil evaporation processes.

Polymaleic acid can be produced through the polymerization of maleic anhydride in an aromatic hydrocarbon medium at temperatures ranging from 60°C to 200°C.

Polymaleic Acid

Product Name:

Polymaleic acid

Synonyms:

Hydrolized polymaleic anhydride;2-Butenedioicacid(Z)-,homopolymer;Hydroxypropylmethacrylamide;HoMopolyMer of Maleic Acid(HPMA);POLY(MALEIC ACID);(z)-2-butenedioic acid homopolymer;poly(maleicacid)(50%aq);MALEIC ACID POLYMER

CAS:

26099-09-2

MF:

C4H4O4

MW:

116.07

EINECS:

607-861-7

Product Categories:

Water treatment;Polymers

Mol File:

26099-09-2.mol

 

Chemical Properties

density 

1.18 (48% aq.)

Fp 

95 °C

storage temp. 

2-8°C

solubility 

Methanol (Sparingly), Water (Soluble)

form 

Pale Yellow to Yellow Solution

Odor

Slight

InChI

InChI=1S/C4H4O4/c5-3(6)1-2-4(7)8/h1-2H,(H,5,6)(H,7,8)/b2-1-

InChIKey

VZCYOOQTPOCHFL-UPHRSURJSA-N

SMILES

C(/C(=O)O)=C/C(=O)O

EPA Substance Registry System

Maleic acid homopolymer (26099-09-2)

Safety Information

Hazard Codes 

C,Xi

Risk Statements 

36-43-36/37/38

Safety Statements 

24/25-28-36/37/39-36/37-26

RIDADR 

UN 3265

Product Applications

1. Oil Industry: Polymaleic acid (PMA) can be used in the acidizing treatment of oil wells during petroleum extraction. It helps dissolve carbonate minerals in surrounding rock formations, thereby improving reservoir permeability and facilitating oil flow, which can contribute to increased oil recovery. Additionally, it can help reduce acid-related corrosion of oilfield equipment.

2. Papermaking Industry: PMA can function as a paper-strengthening agent and retention aid. It enhances paper strength through chemical interactions or physical adsorption with cellulose fibers. Furthermore, it promotes the retention of fine fibers and fillers during the papermaking process, improving paper quality and raw material utilization. For example, it can be incorporated into the production of high-strength packaging paper and printing and writing paper.

3. Textile Industry: PMA can be used as an auxiliary agent in textile printing and dyeing processes. It helps improve dye dispersion and promote uniform dye distribution, thereby enhancing dyeing quality. In addition, it can reduce dye aggregation and precipitation on fabric surfaces, minimizing common defects such as uneven coloration and color spots.

4. Other Applications: PMA and its derivatives may also serve as polymerizable monomers or polymer modifiers in the development of other polymeric materials. Their chemical structures can be utilized in polymer synthesis or modification to introduce desirable properties, such as improved hydrophilicity and antifouling performance.

 

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