Hexamethylene diacrylate

Dual Acrylate Functionality: Contains two reactive acrylate groups for crosslinking reactions.

UV Curing Compatibility: Suitable for selected ultraviolet-curable formulations.

Radiation Curing: Can be used in radiation-curable resin systems.

Formulation Flexibility: Compatible with various acrylic-based formulation approaches.

Crosslinking Capability: Helps form crosslinked polymer networks during curing.

Industrial Applications: Relevant to coatings, inks, adhesives and specialty polymer materials.

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Hexamethylene diacrylate Chemical Properties

Melting point 

6°C

Boiling point 

295°C

density 

1.01 g/mL at 25 °C (lit.)

vapor density 

>1 (vs air)

vapor pressure 

<0.01 mm Hg ( 20 °C)

refractive index 

n20/D 1.456(lit.)

Fp 

>230 °F

storage temp. 

under inert gas (nitrogen or Argon) at 2–8 °C

solubility 

Chlroform (Slightly), DMSO (Slightly)

form 

Liquid

color 

Colourless

Specific Gravity

1.01

Water Solubility 

Slightly miscible with water.

Sensitive 

Hygroscopic

Stability:

Light Sensitive

InChIKey

FIHBHSQYSYVZQE-UHFFFAOYSA-N

LogP

2.81 at 25℃

CAS DataBase Reference

13048-33-4(CAS DataBase Reference)

NIST Chemistry Reference

Hexamethylene diacrylate(13048-33-4)

EPA Substance Registry System

1,6-Hexanediol diacrylate (13048-33-4)

 Safety Information

Hazard Codes 

Xi

Risk Statements 

36/38-43

Safety Statements 

39

RIDADR 

UN 3082 9/PG 3

WGK Germany 

2

RTECS 

AT1430000

TSCA 

Yes

HazardClass 

9

PackingGroup 

III

HS Code 

29161290

Hazardous Substances Data

13048-33-4(Hazardous Substances Data)

Product Overview

Hexamethylene Diacrylate (HDDA), also known as 1,6-Hexanediol Diacrylate, is a difunctional acrylate monomer containing two polymerizable carbon-carbon double bonds. Its molecular structure combines a six-carbon aliphatic spacer with two acrylate functional groups, making it useful as a reactive component in UV-curable and radiation-curable formulations.

HDDA participates in free-radical polymerization and can contribute to the formation of crosslinked polymer structures. It is commonly considered for use in UV-curable coatings, printing inks, adhesives and other specialty resin systems. Its suitability depends on the formulation, curing conditions and the properties required in the finished material.

Hexamethylene Diacrylate is generally produced through the esterification of 1,6-hexanediol with acrylic acid or an acrylic acid derivative. The resulting material is processed and purified to meet the required product specifications. Commercial products may contain polymerization inhibitors to help maintain stability during storage and transportation.

Safety and Storage

Hexamethylene Diacrylate is a reactive acrylate monomer. Direct contact may cause skin or eye irritation and allergic skin reactions. Avoid inhalation of mist or vapor and use appropriate protective equipment and ventilation. Store in a tightly closed, compatible container under the conditions specified in the supplier's Safety Data Sheet (SDS). Protect from excessive heat and direct sunlight. Follow the supplier's recommendations regarding inhibitor content and storage conditions.

Hexamethylene Diacrylate

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