Polypropylene CAS# 9003-07-0

1.Flexible Manufacturing Processes: Polypropylene can be produced using various polymerization methods, allowing its properties to be tailored to different industrial requirements.

2.Dominant Isotactic Structure: Isotactic polypropylene accounts for the majority of commercial applications, valued for its balanced mechanical strength, chemical resistance, and processability.

3.Versatile Atactic PP Applications: With its high viscosity, good flow characteristics, and adhesive properties, atactic polypropylene is suitable for use in masterbatches, coatings, and adhesive formulations.

4.Promising Elastomer Performance: Syndiotactic polypropylene offers good transparency, toughness, and elasticity, making it a potential material for specialized elastomer applications.

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Product Description

Polypropylene (PP) is a high-molecular polymer formed by polymerizing propylene monomers. Manufacturers rely on five mainstream polymerization processes to produce it: solution, slurry, bulk, gas-phase, and integrated bulk-gas-phase polymerization.

In terms of stereochemical structure, PP is grouped into three types: isotactic, syndiotactic and atactic variants. Isotactic PP is the most widely traded grade, making up more than 90% of total market usage.

Atactic polypropylene finds use in additives, binders and polymeric modifiers. Its thick consistency, favorable flow behavior and outstanding covering ability make it an excellent base material for functional masterbatches. Syndiotactic PP delivers clear transparency, strong toughness and good pliability. On the flip side, its rigidity and hardness are only around half that of isotactic PP. Like EPDM rubber, it can undergo vulcanization to create elastomers with mechanical performance superior to standard rubber.

Its relatively high manufacturing cost prevents large-scale application for the time being. Even so, it has great market potential. It stands out as a fast-growing subcategory of polyolefin products and a novel synthetic resin for high-end material modification.

Polypropylene

Chemical Properties

English NamePolypropylene
English SynonymsPROPYLENE RESIN;PROPYLENE, ISOTACTIC RESIN;POLYPROPYLENE;POLYPROPYLENE, ATACTIC;POLYPROPY LENE, PSS NANOREINFORCED;POLYPROPYLENE, ISOTACTIC;Polypropylene master batch,flame retarding;Po lypropylene,film grade
CAS Number9003-07-0
Molecular FormulaC22H4203
Molecular Weight42.08
EINECS Number202-316-6
Melting point157 °C
Boiling point120-132 °C
Density0.9 g/mL at 25 °C (lit.)
Refractive indexn20/D 1.49 (lit.)
Flash point>470
Storage conditions-20°C
AppearanceParticles (spherical)
Colorred
Odor (Odor)Odorless
Biological originhuman
Merck137,663

Product Application

Polypropylene (PP) is a versatile thermoplastic widely applied in packaging, labeling, textiles and other sectors. Its easy processability and cost advantage make it one of the most mass-produced polymers, with substantial demand from the automotive industry.

Unmodified PP can resist photo-oxidation and thermal oxidation under mild temperature conditions. Nevertheless, it is vulnerable to aging triggers including heat, light and radiation, which limits its usable temperature range.

When exposed to high heat or irradiation, the tertiary hydrogen atoms along PP molecular chains are prone to oxidation by oxygen. For outdoor exposure, PP degradation is jointly driven by light and heat. It is also susceptible to photodegradation under ultraviolet light with wavelengths between 310 nm and 350 nm.

Polypropylene

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