Sodium benzoate CAS#532-32-1

Sodium benzoate CAS#532-32-1

  • High-efficiency preservative: Inhibits various microorganisms, works best in acidic conditions for food and beverage preservation.
  • Food-safe additive: Non-toxic at recommended doses, no bioaccumulation, fully excreted with urine.
  • Broad uses: Suitable for soda drinks, fruit juice, jam, jelly, margarine, soy sauce, gum base and other products.
  • Stable & cost-effective: Low cost, odorless or lightly scented, air-stable and slightly hygroscopic for industrial applications.
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Products Description of Sodium benzoate CAS#532-32-1

In 1870, British scientist H. Fleck discovered and documented the antiseptic properties of sodium benzoate while searching for an acid substitute for salicylic acid. He confirmed its antiseptic activity. Nevertheless, due to limited safety‑related research and immature manufacturing techniques at that time, sodium benzoate was not adopted for food preservation until the early 20th century. Thanks to its cost‑competitive advantage, it has since grown into one of the most widely‑utilized preservatives across the globe.

Sodium benzoate is a prevalent food preservative within China’s food‑processing industry. It is virtually odorless or bears a faint benzoin‑like aroma, with a sweet‑astringent taste. The compound remains stable under ambient air conditions yet is capable of absorbing moisture upon prolonged air exposure.

Sodium benzoate occurs naturally in blueberries, apples, plums, cranberries, prunes, cinnamon and cloves. Its bactericidal potency is lower than that of benzoic acid: 1.180 g of sodium benzoate delivers roughly the same bactericidal effect as 1 g of benzoic acid. It exhibits pronounced inhibitory activity against diverse microorganisms under acidic conditions. At pH 3.5, a 0.05 % concentration can fully suppress yeast proliferation. However, its performance against numerous molds and yeasts declines markedly when pH rises above 5.5, and it shows barely any inhibitory effect in alkaline media.

Upon ingestion by humans, sodium benzoate undergoes biological transformation: it conjugates with glycine to generate hippuric acid, or binds with glucuronic acid to form glucuronide metabolites. These metabolites are entirely eliminated via urinary excretion without bodily accumulation. Within permitted dosage limits, it exerts no toxic impacts on human health, classifying it as a relatively safe preservative. It finds application in carbonated beverages, concentrated fruit juices, margarine, gum base, jams, jellies, soy sauce and other products. Its acceptable daily intake (ADI) for humans is less than 5 mg per kilogram of body weight, calculated on a benzoic‑acid basis.

Sodium benzoate Chemical Properties

Melting point >300 °C (lit.)
density 1,44 g/cm3
vapor pressure 0Pa at 20℃
FEMA 3025 | SODIUM BENZOATE
Fp >100°C
storage temp. room temp
solubility H2O: 1 M at 20 °C, clear, colorless
pka4.03[at 20 ℃]
form Crystals, Granules, Flakes or Crystalline Powder
color White
PH7.0-8.5 (25℃, 1M in H2O)
Odorodorless
Water Solubility soluble
Merck 14,8582
BRN 3572467
Stability:Stable, but may be moisture senstive. Incompatible with strong oxidizing agents, alkalis, mineral acids.
InChIKeyWXMKPNITSTVMEF-UHFFFAOYSA-M
LogP1.88
CAS DataBase Reference532-32-1(CAS DataBase Reference)
NIST Chemistry ReferenceSodium benzoate(532-32-1)
EPA Substance Registry SystemSodium benzoate (532-32-1)

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