Methanol CAS#67-56-1

  • Versatile basic raw material, widely used in formaldehyde, methyl ester, solvent and fuel additive production

  • Excellent dissolving performance, miscible freely with water and most organic solvents

  • Low surface tension, good penetration and cleaning effect for industrial cleaning formulations

  • Competitive cost compared with many other alcohol solvents, suitable for large-volume industrial applications

  • High purity industrial grade stable supply, consistent specification for continuous production

  • Important feedstock for biodiesel, MTO, and many fine chemical intermediates

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Products Description

Methanol, also known as methyl alcohol or wood alcohol, is the simplest aliphatic alcohol. It is a colorless, flammable, and volatile liquid with a boiling point of approximately 64.7°C, a melting point of -93.9°C, and a relative density of 0.7913. It is miscible with water and most organic solvents. However, methanol is highly toxic and can cause severe damage to the optic nerve. Ingestion may result in permanent blindness or even death.

Methanol exhibits the typical chemical properties of primary aliphatic alcohols. Its carbon-bound hydrogen atoms can undergo successive oxidation reactions, producing formaldehyde, formic acid, and ultimately carbon dioxide. Consequently, methanol is widely used as a key raw material in the production of formaldehyde. It can also be converted into important organic synthesis intermediates, including methyl formate, methyl chloride, and methylamine. Furthermore, methanol is commonly employed as an organic solvent, an extraction agent, and an alcohol denaturant.

Methanol

Chemical Properties

Melting point 

-98 °C(lit.)

Boiling point 

65.4 °C(lit.)

density 

0.791 g/mL at 25 °C

vapor density 

1.11 (vs air)

vapor pressure 

410 mm Hg ( 50 °C)

refractive index 

n20/D20/D 1.329(lit.)

Fp 

52 °F

storage temp. 

2-8°C

solubility 

benzene: miscible(lit.)

pka

15.2(at 25℃)

form 

Liquid Free From Particulates

Specific Gravity

0.793 (20/20℃)

color 

<10(APHA)

Odor

Faint alcohol odor detectable at 4 to 6000 ppm (mean = 160 ppm)

Relative polarity

0.762

explosive limit

5.5-44%(V)

Odor Threshold

33ppm

Water Solubility 

miscible

λmax

λ: 210 nm Amax: 0.50
λ: 220 nm Amax: 0.30
λ: 230 nm Amax: 0.15
λ: 235 nm Amax: 0.10
λ: 240 nm Amax: 0.05
λ: 260 nm Amax: 0.01
λ: 400 nm Amax: 0.01

Merck 

14,5957

BRN 

1098229

Henry's Law Constant

4.99 at 25 °C (headspace-GC, Gupta et al., 2000)

Exposure limits

TLV-TWA (200 ppm) (ACGIH), 260mg/m3, 1040mg/m3 (800 ppm) 15minutes (NIOSH); STEL 310mg/m3 (250 ppm); IDLH 25,000 ppm (NIOSH).

Dielectric constant

33.6(20℃)

LogP

-0.770

CAS DataBase Reference

67-56-1(CAS DataBase Reference)

NIST Chemistry Reference

Methyl alcohol(67-56-1)

EPA Substance Registry System

Methanol (67-56-1)

Safety Information

Hazard Codes 

Xn,T,F

Risk Statements 

10-20/21/22-68/20/21/22-39/23/24/25-23/24/25-11-40-36-36/38-23/25

Safety Statements 

36/37-7-45-16-24/25-23-24-26

RIDADR 

UN 1170 3/PG 2

OEB

A

OEL

TWA: 200 ppm (260 mg/m3), STEL: 250 ppm (325 mg/m3) [skin]

WGK Germany 

1

RTECS 

PC1400000

F 

3-10

Autoignition Temperature

385 °C

TSCA 

Yes

HS Code 

2905 11 00

HazardClass 

3

PackingGroup 

II

Hazardous Substances Data

67-56-1(Hazardous Substances Data)

Toxicity

LD50 oral (rat)
5628 mg/kg
LD50 skin (rabbit)
15,840 mg/kg
LC50 inhal (rat)
>145,000 ppm (1 h)
PEL (OSHA)
200 ppm (260 mg/m3)
TLV-TWA (ACGIH)
200 ppm (260 mg/m3)—skin
STEL (ACGIH)
250 ppm (328 mg/m3)

IDLA

6,000 ppm

Product Applications

Methanol is an important raw material in the production of fine chemicals and various industrial products. Through catalytic carbonylation at temperatures of 180–200°C and a pressure of approximately 3.5 MPa, methanol can be converted into acetic acid, which can be further processed to produce acetic anhydride. It can also react with synthesis gas (syngas) to produce vinyl acetate in the presence of a catalyst. Other important derivatives include methyl tert-butyl ether (MTBE), obtained through its reaction with isobutylene, and dimethyl oxalate, which can be produced through oxidation and carbonylation. Further hydrogenation of dimethyl oxalate yields ethylene glycol. Additionally, methanol can react with toluene under catalytic conditions, followed by oxidation, to produce phenylethyl alcohol.

Beyond its role as a chemical intermediate, methanol has a wide range of industrial applications. It is used as an organic solvent, a raw material for pesticide production, an antifreeze agent, and a fuel or fuel additive, with increasing interest in its potential environmental applications. Methanol is also a primary feedstock for formaldehyde production and is widely utilized in the manufacture of pharmaceuticals, fragrances, and other fine chemicals. Furthermore, it serves as a solvent in the dye and paint industries and as a raw material for producing methanol-derived single-cell protein and methyl esters.

 

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